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2015

 

38.  Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

Shao, X.-X.; Xu, C.-F.; Lu, L.; Shen, Q. Acc. Chem. Res. 2015, 48, asap, DOI: 10.1021/acs.accounts.5b00047.

 

37. Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts

Wu, J.; Gu, Y.; Leng, X.-B.; Shen, Q. Angew. Chem. Int. Ed. 2015, 54, accepted, DOI: 10.1002/anie.20152113.

 

36. Pd-Catalyzed difluoromethylation of Vinyl Bromides, Tosylates and Nonaflates

Chang, D.-L.;  Gu, Y.; Shen, Q. Chem. Eur. J. 2015, 21, 6074

 

35. Iron-Catalyzed Markovnikov-Selective Hydrotrifluoromethylthiolation of Unacti-vated Alkenes

Yang, T.;  Lu, L.; Shen, Q. Chem. Commun. 2015, 51, 5479 .

 

34. Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent

Shao, X.-X.; Xu, C.-F.; Lu, L.; Shen, Q. J. Org. Chem. 2015 80, 3012 .

 

33. BrØsted Acid-Catalyzed Electrophilic Trifluoromethylthiolation of Indoles Using Thermally Stable Trifluoromethylthiolating Reagent

Ma, B.-Q.; Shao, X.-X.; Shen, Q. J. Fluorine Chem. 2015, 171, 73.
 

2014

 

32.  Cooperative Dual Palladium/Silver Catalyst for Direct Difluoromethylation of aryl Bromides and Iodides

Gu, Y.; Leng, X.-B.; Shen, Q. Nat. Commun. 2014, 5, 5405, doi: 10.1038/ncomms 6405.

 

31. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion

Hu, F.; Shao, X.-X.; Zu, D.-H.; Lu, L.; Shen, Q. Angew. Chem. Int. Ed. 2014, 53, 6105

 

30. N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

Xu, C.-F.; Ma, B.-Q.; Shen, Q. Angew. Chem. Int. Ed. 2014, 53, 9316

 

29.  Palladium-Catalyzed Trifluoromethylthiolation of Aryl C−H Bonds

Xu, C.-F.; Shen, Q. Org. Lett. 2014, 16, 2046

 

28.  Copper-Catalyzed Trifluoromethylthiolation of Primary and Secondary Alkylboronic Acids

Shao, X.-X.; Liu, T.-F.; Lu, L.; Shen, Q. Org. Lett. 2014, 16, 4738

 

27.  Nickel-Catalyzed α-Arylation of Zinc Enolates with Polyfluoroarenes via C–F Bond Activation under Neutral Conditions

Yu, D.-H.; Wang, C.-S.; Yao, C.; Shen, Q.; Lu, L. Org. Lett. 2014, 16, 5544.

 

26. Copper-catalyzed Trifluoromethylthiolation of Aryl and Vinyl Boronic Acids with a Shelf-Stable Electrophilic Trifluoromethylthiolating Reagent

Kang, K.; Xu, C.-F.; Shen, Q. Org. Chem. Front. 2014, 1, 294

 

25.  Chincona Alkaloid-Catalyzed Enantioselective Trifluoromethylthiolation of Oxindoles

Yang, T.; Shen, Q.; Lu, L. Chin. J. Chem. 2014, 32, 678

 

2013

 

24. An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

Shao, X.-X.; Wang, X.-Q.; Yang, T.; Long Lu, L. Shen, Q. Angew. Chem. Int. Ed. 2013, 52, 3457

 

23. Enantioselective Electrophilic Trifluoromethylthiolation of b-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

Wang, X.-Q.; Tao Yang, T.; Xiaolin Cheng, X.-L.; Shen, Q. Angew. Chem. Int. Ed. 2013, 52, 12860

 

22. Palladium-Catalyzed Coupling of Polyfluorinated Arenes with Heteroarenes via C_F/C_H Activation

Yu, D.-H.; Lu, L.; Shen, Q. Org. Lett. 2013, 15, 940

 

21.  Enantioselective Organocatalytic Michael Addition of Nitroalkanes and Other Nucleophiles to βTrifluoromethylated Acrylamides

Wen, L.-L.; Yin, L.; Shen, Q.; Lu, L. ACS Catal. 2013, 3, 502

 

20. Palladium-Catalyzed Cross-Coupling of Fluorinated Vinyl Chlorides with Terminal Alkynes: A General Protocol to Fluorinated Enynes

Chen, S.; Xu, C.-F.; Lu, L.; Shen, Q. Chin. J. Chem. 2013, 31, 901

 

19. A General and Highly Selective Method for the Asymmetric Synthesis of Trifluoromethyl-Substituted α- and β-Aminophosphonates

Wang, L.-J.; Shen, Q.; Lu, L.  Chin. J. Chem. 2013, 31, 892.

 

2012

 

18. Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

Liu, T.-F.; Shao, X.-X.; Wu, Y.-M.; Shen, Q. Angew. Chem. Int. Ed. 2012, 51, 540. 

 

17. Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature

Qi, Q.-Q.; Shen, Q.; Lu, L. J. Am. Chem. Soc. 2012, 134, 6548.

 

16. Bis(perfluoroalkyl) Phosphino-Oxazoline: A Modular, Stable, Strongly πAccepting Ligand for Asymmetric Catalysis

Hu, Z.-J.; Li, Y.-G.; Liu, K.; Shen, Q.  J. Org. Chem. 2012, 77, 7957

 

15. Selective Palladium-Catalyzed C−F Activation/Carbon−Carbon Bond Formation of Polyfluoroaryl Oxazolines

Yu, D.-H.; Shen, Q.; Lu, L. J. Org. Chem. 2012, 77, 1798

 

14. Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Aryl Boronic Acids with Chloro- and Bromo-Trifluoroethylene

Xu, X.-F.; Chen, S.; Lu, L.; Shen, Q. J. Org. Chem. 2012, 77, 10314

 

13. Highly Selective Activation of Vinyl C-S Bond over Aryl C-S Bond in Pd-Catalyzed Coupling of Trifluoromethyl-ated Vinyl Diphenyl Sulfonium Salts. A General Protocol to Trifluoromethylated Alkenes and Dienes

Lin, H.; Dong, X.-C.; Li, Y.-X.; Shen, Q.; Lu, L. Eur. J. Org. Chem. 2012, 4675

 

12.  Progresses in Copper-mediated Formation of Trifluoromethylated Arene

Liu, T.-F.; Shen, Q.  Eur. J. Org. Chem. 2012, 6679

 

11. General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction

Liu, T.-P.; Zhao, X.-M.; Shen, Q.; Lu, L. Tetrahedron 201268, 6535 

 

10.  Polyfluoroalkylation of 2-Aminothiazoles

Qi, Q.-Q.; Shen, Q.; Lu, L. J. Fluorine Chem. 2012, 133, 115

 

9.   A Facile Synthetic Route to 2-Trifluromethyl-Substituted Polyfunctionalized Chromenes and Chromones

Wen, L.-L.; Zhang, H.-H.; Lin, L.; Shen, Q.; Lu, L. J. Fluorine Chem. 2012, 133, 177

 

8.    Transition metal-catalyzed arene trifluoromethylation

Lv, C.-P.; Shen, Q.; Liu, D. Youji Huaxue 2012, 32, 1380

 

7.   General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction

Liu, T.-P.; Zhao, X.-M.; Shen, Q.; Lu, L. Tetrahedron 201268, 6535 

 

2011

 

6.   Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

Liu, T.; Shen, Q. Org. Lett. 2011, 13, 2342

 

5.  (β-Trifluoromethyl)Vinyl Sulfonium Salts: Preparation and Reactions with Active Methylene and Methenyl Compounds

Lin, H.; Shen, Q.; Lu, L. J. Org. Chem. 2011, 76, 7359

 

4.   Enantioselective Friedel-Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper-Bis(Oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center

Wen, L.; Shen, Q.; Wan, X.; Lu, L. J. Org. Chem. 2011, 76, 2282

 

3. Highly Diastereoselective Synthesis of Optically Pure Trifluoromethyl-Substituted Imidazolidine, Oxazolidine and Thiazolidine

Zhang, H.; Shen, Q.; Lu, L. Tetrahedron Lett. 2011, 52, 349

 

2.  The Recent Development of Organofluorine Chemistry in China: Asymmetric Construction of Stereogenic Trifluoromethyl-Substituted Carbon Center

Wen, L.; Shen, Q.; Lu, L. Chimia 2011, 65, 894

 

1.  Polyfluoroalkylation of 2-Aminothiazoles: Unexpected sp3 C-Cl Substitution Under Mild Conditions

Qi, Q.; Shen, Q.; Lu, L. Chinese J. Chem. 2011, 29, 2681

 

 

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